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Perspective of mixed matrix membranes for carbon capture

Shinji Kanehashi, Colin A. Scholes

《化学科学与工程前沿(英文)》 2020年 第14卷 第3期   页码 460-469 doi: 10.1007/s11705-019-1881-5

摘要: Polymeric membrane-based gas separation has found wide applications in industry, such as carbon capture, hydrogen recovery, natural gas sweetening, as well as oxygen enrichment. Commercial gas separation membranes are required to have high gas permeability and selectivity, while being cost-effective to process. Mixed matrix membranes (MMMs) have a composite structure that consists of polymers and fillers, therefore featuring the advantages of both materials. Much effort has been made to improve the gas separation performance of MMMs as well as general membrane properties, such as mechanical strength and thermal stability. This perspective describes potential use of MMMs for carbon capture applications, explores their limitations in fabrication and methods to overcome them, and addresses their performance under industry gas conditions.

关键词: membranes     polymeric     mixed matrix     impurities    

G-CNTs/PVDF mixed matrix membranes with improved antifouling properties and filtration performance

Xiaoyan Guo, Chunyu Li, Chenghao Li, Tingting Wei, Lin Tong, Huaiqi Shao, Qixing Zhou, Lan Wang, Yuan Liao

《环境科学与工程前沿(英文)》 2019年 第13卷 第6期 doi: 10.1007/s11783-019-1165-9

摘要:

A novel nanocomposite OMWCNT-A-GO was synthesized by conjugating OMWCNT and GO.

The P-OMWCNT-A-GO membrane was fabricated by non-solvent induced phase inversion.

The P-OMWCNT-A-GO exhibits the best water flux, BSA rejection and flux recovery.

It should be due to the enhanced membrane pore size, porosity and hydrophilicity.

关键词: carbon nanotubes     graphene oxide     mixed matrix membrane     nanohybrid     antifouling membrane     membrane hydrophilicity    

含氧化石墨烯混合基质反渗透复合膜的制备及性能研究

芦瑛,赵海洋,张林,侯立安

《中国工程科学》 2014年 第16卷 第7期   页码 84-88

摘要:

以间苯二胺(MPD)为水相单体、均苯三甲酰氯(TMC)为油相单体,氧化石墨烯(GO)作为水相添加物,采用界面聚合法,制备了GO-PA(聚酰胺)/PSF(聚砜)混合基质反渗透复合膜。采用扫描电子显微镜表征了膜形貌,考察了该膜对氯化钠的截留性能及耐氯性。结果表明,聚酰胺反渗透膜填充氧化石墨烯后,其分离性能优于聚酰胺膜,且具有较好的耐氯性。随着氧化石墨烯含量的增加,膜的通量增大,当添加量为0.005 %时,膜具有最大通量,为63 L/(m2·h)。

关键词: 氧化石墨烯     聚酰胺     混合基质膜     反渗透     耐氯性    

Influence of surface modified mixed metal oxide nanoparticles on the electrochemical and mechanical propertiesof polyurethane matrix

《化学科学与工程前沿(英文)》 2023年 第17卷 第1期   页码 1-14 doi: 10.1007/s11705-022-2176-9

摘要: Newly synthesized functional nanoparticles, 3-amino-1,2,4-triazole (ATA)/SiO2–TiO2 were introduced to the polyurethane (PU) matrix. Electrochemical techniques were used to investigate the barrier properties of the synthesized PU–ATA/SiO2–TiO2 nanocomposite coated steel specimen. In natural seawater, electrochemical impedance spectroscopy experiments indicated outstanding protective behaviour for the PU–ATA/SiO2–TiO2 coated steel. The coating resistance (Rcoat) of PU–ATA/SiO2–TiO2 was determined to be 2956.90 kΩ·cm–2. The Rcoat of the PU–ATA/SiO2–TiO2 nanocomposite coating was found to be over 50% higher than the PU coating. The current measured along the scratched surface of the PU–ATA/SiO2–TiO2 coating was found to be very low (1.65 nA). The enhanced ATA/SiO2–TiO2 nanoparticles inhibited the entry of electrolytes into the coating interface, as revealed by scanning electron microscopy/energy dispersive X-ray spectroscopy and X-ray diffraction analysis of the degradation products. Water contact angle testing validated the hydrophobic nature of the PU–ATA/SiO2–TiO2 coating (θ = 115.4°). When the concentration of ATA/SiO2−TiO2 nanoparticles was 2 wt %, dynamic mechanical analysis revealed better mechanical properties. Therefore, the newly synthesised PU–ATA/SiO2–TiO2 nanocomposite provided excellent barrier and mechanical properties due to the addition of ATA/SiO2–TiO2 nanoparticles to the polyurethane, which inhibited material degradation and aided in the prolongation of the coated steel’s life.

关键词: SiO2/TiO2 nanoparticle     nanocomposite coatings     dynamic mechanical analysis     electrochemical techniques     corrosion     colloids and interfaces    

用于气体分离的含多孔材料的混合基质膜——从金属有机框架到离散分子笼 Review

杨子琪, 吴中杰, 白胜博, 应允攀, 杨昊, 赵丹

《工程(英文)》 2023年 第23卷 第4期   页码 40-55 doi: 10.1016/j.eng.2022.07.022

摘要:

混合基质膜(MMMs)将多孔材料与聚合物基质结合,因二者的互补性和协同作用,MMMs在气体分离研究领域得到了广泛关注。多孔材料的可调节性和多样性赋予了MMMs可扩展的功能和优异的分离性能。为了充分发挥MMMs的潜力,研究人员专注于多孔填料与聚合物基质的合理匹配,以提高MMMs的
界面相容性。在本文中,我们重点介绍了利用不同策略,将金属有机框架(MOFs)或金属有机笼(MOCs)与聚合物基质相结合,以制备MMMs的最新进展,并且进一步讨论了MMMs未来发展所面临的机遇和挑战,这将通过合理的材料设计和选择促进MMMs的发展。

关键词: 气体分离     金属-有机框架     金属-有机笼     混合基质膜     界面相容性    

Effect of TiO

Navid Azizi, Mojgan Isanejad, Toraj Mohammadi, Reza M. Behbahani

《化学科学与工程前沿(英文)》 2019年 第13卷 第3期   页码 517-530 doi: 10.1007/s11705-018-1781-0

摘要: Membranes have attracted much attention as economical methods for industrial chemical processes. The effects of the titanium dioxide nanoparticle load on the morphology and CO /CH separation performance of poly (ether-block-amide) (PEBAX-1657) mixed matrix membranes (MMMs) were investigated from pressures of 3–12 bar and temperatures of 30°C–60°C. The PEBAX membranes were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, thermal gravimetric analysis, atomic force microscopy and tensile strength analysis. The incorporation of TiO nanoparticles into the polymeric MMMs improved the CO /CH gas separation performance (both the permeability and selectivity) of the membranes. The CO permeability and ideal CO /CH selectivity values of the nanocomposite membrane loaded with 8 wt-% TiO were 172.32 Barrer and 24.79, respectively whereas those of the neat membrane were 129.87 Barrer and 21.39, respectively.

关键词: mixed matrix membrane     TiO2 nanoparticles     PEBAX-1657     CO2/CH4 separation    

Iteration framework for solving mixed lubrication computation problems

《机械工程前沿(英文)》 2021年 第16卷 第3期   页码 635-648 doi: 10.1007/s11465-021-0632-8

摘要: The general discrete scheme of time-varying Reynolds equation loses the information of the previous step, which makes it unreasonable. A discretization formula of the Reynolds equation, which is based on the Crank–Nicolson method, is proposed considering the physical message of the previous step. Gauss–Seidel relaxation and distribution relaxation are adopted for the linear operators of pressure during the numerical solution procedure. In addition to the convergent criteria of pressure distribution and load, an estimation framework is developed to investigate the relative error of the most important term in the Reynolds equation. Smooth surface with full contacts and mixed elastohydrodynamic lubrication is tested for validation. The asperity contact and sinusoidal wavy surface are examined by the proposed discrete scheme. Results show the precipitous decline in the boundary of the contact area. The relative error suggests that the pressure distribution is reliable and reflects the accuracy and effectiveness of the developed method.

关键词: mixed lubrication     discretization formula     relative error     Reynolds equation     asperity    

Decellularized extracellular matrix mediates tissue construction and regeneration

《医学前沿(英文)》 2022年 第16卷 第1期   页码 56-82 doi: 10.1007/s11684-021-0900-3

摘要: Contributing to organ formation and tissue regeneration, extracellular matrix (ECM) constituents provide tissue with three-dimensional (3D) structural integrity and cellular-function regulation. Containing the crucial traits of the cellular microenvironment, ECM substitutes mediate cell–matrix interactions to prompt stem-cell proliferation and differentiation for 3D organoid construction in vitro or tissue regeneration in vivo. However, these ECMs are often applied generically and have yet to be extensively developed for specific cell types in 3D cultures. Cultured cells also produce rich ECM, particularly stromal cells. Cellular ECM improves 3D culture development in vitro and tissue remodeling during wound healing after implantation into the host as well. Gaining better insight into ECM derived from either tissue or cells that regulate 3D tissue reconstruction or organ regeneration helps us to select, produce, and implant the most suitable ECM and thus promote 3D organoid culture and tissue remodeling for in vivo regeneration. Overall, the decellularization methodologies and tissue/cell-derived ECM as scaffolds or cellular-growth supplements used in cell propagation and differentiation for 3D tissue culture in vitro are discussed. Moreover, current preclinical applications by which ECM components modulate the wound-healing process are reviewed.

关键词: decellularized extracellular matrix     3D culture     organoids     tissue repair    

new regeneration approach to cation resins with aluminum salts: application of desalination by its mixed

Zhigang LIU, Shaomin ZHU, Yansheng LI

《环境科学与工程前沿(英文)》 2012年 第6卷 第1期   页码 45-50 doi: 10.1007/s11783-010-0262-6

摘要: A novel method for the regeneration of cation exchange resins by aluminum (Al) salts was investigated in order to improve the regeneration efficiency of resins and reduce the dosage of regenerant. The influences of Al concentration and the pH of regeneration solution on resin transformation had been studied. The desalination experiments were carried out to evaluate the characteristics of the Al form resins. Experimental results showed that the regeneration rate of resins was strictly dependent on Al concentration and the pH of the solution. Compared to the conventional regeneration method, the Al form mixed bed exhibited the same desalination capability as the H form mixed bed (MB), and the total organic carbon (TOC) removal was up to 90%, clearly higher than that of the H form. Al salt solution could be utilized repeatedly to regenerate Al form resins.

关键词: aluminum (Al) form resins     desalination     mixed bed (MB)     regeneration    

characteristics and daily fluctuations of microplastics throughout wastewater treatment plants with mixed

《环境科学与工程前沿(英文)》 2022年 第16卷 第1期   页码 6-6 doi: 10.1007/s11783-021-1440-4

摘要:

• MPs were analyzed throughout three WWTPs with mixed domestic–industrial influents.

关键词: Microplastic     Wastewater treatment plant     Mixed domestic-industrial influent     Characteristic     Daily fluctuation    

Scrap Iron Filings assisted nitrate and phosphate removal in low C/N waters using mixed microbial culture

《环境科学与工程前沿(英文)》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1358-2

摘要:

• Microbes enhance denitrification under varying DO concentrations and SIF dosages.

关键词: Scrap iron filing     Nitrate removal     Phosphate removal     Mixed culture denitrification     Zero valent iron    

Strengthening of reinforced concrete beams using fiber-reinforced cementitious matrix systems fabricated

《结构与土木工程前沿(英文)》   页码 1100-1116 doi: 10.1007/s11709-023-0967-9

摘要: The performance of a new fiber-reinforced cementitious matrix (FRCM) system developed using custom-designed mortar and fabrics is investigated in this study. The behavior of this system is evaluated in terms of both the flexural and shear strengthening of reinforced concrete beams. Eight beams are designed to assess the effectiveness of the FRCM system in terms of flexural strengthening, and four specimens are designed to investigate their shear behavior. The parameters investigated for flexural strengthening are the number of layers, span/depth ratio, and the strengthening method. Unlike previous studies, custom fabrics with similar axial stiffness are used in all strengthening methods in this study. In the shear-strengthened specimens, the effects of the span/depth ratio and strengthening system type (fiber-reinforced polymer (FRP) or FRCM) are investigated. The proposed FRCM system exhibits desirable flexural and shear strengthening for enhancing the load capacity, provides sufficient bonding with the substrate, and prevents premature failure modes. Considering the similar axial stiffness of fabrics used in both FRCM and FRP systems and the higher load capacity of specimens strengthened by the former, cement-based mortar performs better than epoxy.

关键词: fiber-reinforced cementitious matrix     flexural strengthening     shear strengthening     carbon fiber-reinforced polymer     shear span    

Fluoride ions adsorption from water by CaCO enhanced Mn–Fe mixed metal oxides

《化学科学与工程前沿(英文)》 2023年 第17卷 第2期   页码 236-248 doi: 10.1007/s11705-022-2193-8

摘要: Novel CaCO3-enhanced Mn–Fe mixed metal oxides (CMFC) were successfully prepared for the first time by a simple-green hydrothermal strategy without any surfactant or template combined with calcination process. These oxides were then employed as an adsorbent for adsorptive removal of excess fluoride ions. The adsorbent was characterized by SEM, XPS, XRD, FTIR, and BET analysis techniques. The adsorption property of CMFC toward fluoride ion was analyzed by batch experiments. In fact, CMFC exhibited adsorption capacity of 227.3 mg∙g‒1 toward fluoride ion. Results showed that ion exchange, electrostatic attraction and chemical adsorption were the main mechanism for the adhesion of large amount of fluoride ion on the CMFC surface, and the high adsorption capacity responded to the low pH of the adsorption system. When the fluoride ion concentration was increased from 20 to 200 mg∙L‒1, Langmuir model was more in line with experimental results. The change of fluoride ion adsorption with respect to time was accurately described by pseudo-second-order kinetics. After five cycles of use, the adsorbent still maintains a performance of 70.6% of efficiency, compared to the fresh adsorbent. Therefore, this material may act as a potential candidate for adsorbent with broad range of application prospects.

关键词: mesoporous materials     metal oxides     fluoride ion     adsorption mechanism    

Optimization and modeling of biohydrogen production by mixed bacterial cultures from raw cassava starch

Shaojie Wang,Zhihong Ma,Ting Zhang,Meidan Bao,Haijia Su

《化学科学与工程前沿(英文)》 2017年 第11卷 第1期   页码 100-106 doi: 10.1007/s11705-017-1617-3

摘要: The production of bio-hydrogen from raw cassava starch via a mixed-culture dark fermentation process was investigated. The production yield of H was optimized by adjusting the substrate concentration and the microorganism mixture ratio. A maximum H yield of 1.72 mol H /mol glucose was obtained with a cassava starch concentration of 10 g/L to give a 90% utilization rate. The kinetics of the substrate utilization and of the generation of both hydrogen and volatile fatty acids were also investigated. The substrate utilization follows pseudo first order reaction kinetics, whereas the production of both H and the VFAs correlate with the Gompertz equation. These results show that cassava is a good candidate for the production of biohydrogen.

关键词: cassava     biohydrogen     mixed cultures     kinetics    

标题 作者 时间 类型 操作

Perspective of mixed matrix membranes for carbon capture

Shinji Kanehashi, Colin A. Scholes

期刊论文

G-CNTs/PVDF mixed matrix membranes with improved antifouling properties and filtration performance

Xiaoyan Guo, Chunyu Li, Chenghao Li, Tingting Wei, Lin Tong, Huaiqi Shao, Qixing Zhou, Lan Wang, Yuan Liao

期刊论文

含氧化石墨烯混合基质反渗透复合膜的制备及性能研究

芦瑛,赵海洋,张林,侯立安

期刊论文

Influence of surface modified mixed metal oxide nanoparticles on the electrochemical and mechanical propertiesof polyurethane matrix

期刊论文

用于气体分离的含多孔材料的混合基质膜——从金属有机框架到离散分子笼

杨子琪, 吴中杰, 白胜博, 应允攀, 杨昊, 赵丹

期刊论文

Effect of TiO

Navid Azizi, Mojgan Isanejad, Toraj Mohammadi, Reza M. Behbahani

期刊论文

刘公平:面向CO₂捕集的混合基质膜设计制备(2022年4月16日)

2022年06月09日

会议视频

Iteration framework for solving mixed lubrication computation problems

期刊论文

Decellularized extracellular matrix mediates tissue construction and regeneration

期刊论文

new regeneration approach to cation resins with aluminum salts: application of desalination by its mixed

Zhigang LIU, Shaomin ZHU, Yansheng LI

期刊论文

characteristics and daily fluctuations of microplastics throughout wastewater treatment plants with mixed

期刊论文

Scrap Iron Filings assisted nitrate and phosphate removal in low C/N waters using mixed microbial culture

期刊论文

Strengthening of reinforced concrete beams using fiber-reinforced cementitious matrix systems fabricated

期刊论文

Fluoride ions adsorption from water by CaCO enhanced Mn–Fe mixed metal oxides

期刊论文

Optimization and modeling of biohydrogen production by mixed bacterial cultures from raw cassava starch

Shaojie Wang,Zhihong Ma,Ting Zhang,Meidan Bao,Haijia Su

期刊论文